Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Type
Article

Authors
Lu, Chunjing
Ben, Teng
Xu, Shixian
Qiu, Shilun

KAUST Grant Number
CRG-1-2012-LAI-009

Online Publication Date
2014-05-22

Print Publication Date
2014-06-16

Date
2014-05-22

Abstract
A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

Citation
Lu C, Ben T, Xu S, Qiu S (2014) Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film. Angew Chem 126: 6572–6576. Available: http://dx.doi.org/10.1002/ange.201402950.

Acknowledgements
This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012).

Publisher
Wiley

Journal
Angewandte Chemie

DOI
10.1002/ange.201402950

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