Efficient and Highly Aldehyde Selective Wacker Oxidation
| dc.contributor.author | Teo, Peili | |
| dc.contributor.author | Wickens, Zachary K. | |
| dc.contributor.author | Dong, Guangbin | |
| dc.contributor.author | Grubbs, Robert H. | |
| dc.date.accessioned | 2016-02-25T13:12:38Z | |
| dc.date.available | 2016-02-25T13:12:38Z | |
| dc.date.issued | 2012-06-13 | |
| dc.identifier.citation | Teo P, Wickens ZK, Dong G, Grubbs RH (2012) Efficient and Highly Aldehyde Selective Wacker Oxidation. Organic Letters 14: 3237–3239. Available: http://dx.doi.org/10.1021/ol301240g. | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.issn | 1523-7052 | |
| dc.identifier.pmid | 22694293 | |
| dc.identifier.doi | 10.1021/ol301240g | |
| dc.identifier.uri | http://hdl.handle.net/10754/598098 | |
| dc.description.abstract | A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl 2(MeCN) 2, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates. © 2012 American Chemical Society. | |
| dc.description.sponsorship | We gratefully acknowledge financial support from King Abdullah University of Science and Technology Centre in Development, King Fahd University of Petroleum and Minerals, and the NSF. G.D. thanks the Camille and Henry Dreyfus Foundation for a postdoctoral fellowship. | |
| dc.publisher | American Chemical Society (ACS) | |
| dc.title | Efficient and Highly Aldehyde Selective Wacker Oxidation | |
| dc.type | Article | |
| dc.identifier.journal | Organic Letters | |
| dc.contributor.institution | California Institute of Technology, Pasadena, United States | |
| dc.contributor.institution | Institute of Chemical and Engineering Sciences, Singapore City, Singapore | |
| dc.contributor.institution | University of Texas at Austin, Austin, United States | |
| dc.date.published-online | 2012-06-13 | |
| dc.date.published-print | 2012-07-06 |