Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

Type
Article

Authors
Park, Youngjune
Petit, Camille
Han, Patrick
Alissa Park, Ah-Hyung

KAUST Grant Number
KUS-C1-018-02

Date
2014

Abstract
Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.

Citation
Park Y, Petit C, Han P, Alissa Park A-H (2014) Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials. RSC Adv 4: 8723. Available: http://dx.doi.org/10.1039/c3ra46801a.

Acknowledgements
This publication was based on work supported by Award no. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST).

Publisher
Royal Society of Chemistry (RSC)

Journal
RSC Advances

DOI
10.1039/c3ra46801a

Permanent link to this record