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    Cross-Linkable Polyimide Membranes for Improved Plasticization Resistance and Permselectivity in Sour Gas Separations

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    Type
    Article
    Authors
    Kraftschik, Brian
    Koros, William J.
    Date
    2013-08-29
    Online Publication Date
    2013-08-29
    Print Publication Date
    2013-09-10
    Permanent link to this record
    http://hdl.handle.net/10754/597898
    
    Metadata
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    Abstract
    A series of cross-linkable membrane materials based on the 6FDA-DAM:DABA (3:2) polyimide backbone were synthesized for improved sour gas separation performance, in terms of both membrane stability and permselectivity. Short-chain poly(ethylene glycol) (PEG) molecules were used as cross-linking agents in an esterification-based cross-linking reaction. Pure and mixed gas permeation and pure gas sorption experiments were performed on dense films of these materials. Compared to unmodified 6FDA-DAM:DABA (3:2), higher sour gas permselectivity and membrane stability were achieved under aggressive feed conditions. H2S-induced plasticization was not evident until pure H2S feed pressures greater than approximately 6-8 bar. Pure CO 2-induced plasticization only occurred at feed pressures greater than about 25 bar. Under mixed gas feed conditions with 20% H2S, 20% CO2, and 60% CH4 at 35 C, attractive selectivities above 22 and 27 for H2S/CH4 and CO2/CH4, respectively, were observed for a feed pressure of 62 bar with both triethylene glycol and tetraethylene glycol cross-linking agents. © 2013 American Chemical Society.
    Citation
    Kraftschik B, Koros WJ (2013) Cross-Linkable Polyimide Membranes for Improved Plasticization Resistance and Permselectivity in Sour Gas Separations. Macromolecules 46: 6908–6921. Available: http://dx.doi.org/10.1021/ma401542j.
    Sponsors
    The authors acknowledge the King Abdullah University of Science and Technology (KAUST) for generously funding this work.
    Publisher
    American Chemical Society (ACS)
    Journal
    Macromolecules
    DOI
    10.1021/ma401542j
    ae974a485f413a2113503eed53cd6c53
    10.1021/ma401542j
    Scopus Count
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