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    Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand

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    Type
    Article
    Authors
    Wang, Xiaofang
    Xue, Ming
    Wu, Gang
    Pan, Ying
    Qiu, Shilun
    KAUST Grant Number
    CRG-1-2012-LAI-009
    Date
    2016-02
    Permanent link to this record
    http://hdl.handle.net/10754/597841
    
    Metadata
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    Abstract
    © 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.
    Citation
    Wang X, Xue M, Wu G, Pan Y, Qiu S (2016) Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand. Inorganic Chemistry Communications 64: 31–34. Available: http://dx.doi.org/10.1016/j.inoche.2015.12.004.
    Sponsors
    This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012).
    Publisher
    Elsevier BV
    Journal
    Inorganic Chemistry Communications
    DOI
    10.1016/j.inoche.2015.12.004
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.inoche.2015.12.004
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