CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy
KAUST Grant NumberKUS-C1-018-02
Online Publication Date2011-10-28
Print Publication Date2012-01-12
Permanent link to this recordhttp://hdl.handle.net/10754/597786
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AbstractNovel nanoparticle organic hybrid materials (NOHMs), which are comprised of organic oligomers or polymers tethered to an inorganic nanosized cores of various sizes, have been synthesized, and their solvating property for CO 2 was investigated using attenuated total reflectance (ATR) Fourier transform infrared (FT-IR) spectroscopy. Simultaneous measurements of CO 2 capture capacity and swelling behaviors of polyetheramine (Jeffamine M-2070) and its corresponding NOHMs (NOHM-I-PE2070) were reported at temperatures of (298, 308, 323 and 353) K and CO 2 pressure conditions ranging from (0 to 5.5) MPa. The polymeric canopy, or polymer bound to the nanoparticle surface, showed significantly less swelling behavior with enhanced or comparable CO 2 capture capacity compared to pure unbound polyetheramine. © 2011 American Chemical Society.
CitationPark Y, Shin D, Jang YN, Park A-HA (2012) CO 2 Capture Capacity and Swelling Measurements of Liquid-like Nanoparticle Organic Hybrid Materials via Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy . J Chem Eng Data 57: 40–45. Available: http://dx.doi.org/10.1021/je200623b.
SponsorsThis publication was based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), and the Utilization and Sequestration of CO<INF>2</INF> using Industrial Minerals Program by Korea Institute of Geoscience & Mineral Resources (KIGAM).
PublisherAmerican Chemical Society (ACS)