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partially supported by the NSF-CDI under contract number DMS 0835745, the DOE grant DE-FGO2-04ER25617, and the Center for Frontiers of Subsurface Energy Security under Contract No. DE-SC0001114.supported by Award No. KUS-F1-032-04, made by King Abdullah University of Science and Technology (KAUST).partially supported by the DOE grant DE-FG02-04ER25618, the NSF grant DMS 0813901, and the J. Tinsley Oden Faculty Fellowship, ICES, The University of Texas at Austin.