Facile Synthesis of Colloidal CuO Nanocrystals for Light-Harvesting Applications

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Type
Article
Authors
Lim, Yee-Fun
Choi, Joshua J.
Hanrath, Tobias
Date
2012
Permanent link to this record
http://hdl.handle.net/10754/596995

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Abstract
CuO is an earth-abundant, nontoxic, and low band-gap material; hence it is an attractive candidate for application in solar cells. In this paper, a synthesis of CuO nanocrystals by a facile alcohothermal route is reported. The nanocrystals are dispersible in a solvent mixture of methanol and chloroform, thus enabling the processing of CuO by solution. A bilayer solar cell comprising of CuO nanocrystals and phenyl-C61-butyric acid methyl ester (PCBM) achieved a power conversion efficiency of 0.04%, indicating the potential of this material for light-harvesting applications.
Citation
Lim Y-F, Choi JJ, Hanrath T (2012) Facile Synthesis of Colloidal CuO Nanocrystals for Light-Harvesting Applications. Journal of Nanomaterials 2012: 1–6. Available: http://dx.doi.org/10.1155/2012/393160.
Sponsors
This work was funded by the KAUST-Cornell Center for Energy and Sustainability. The authors thank Dr. Jacek Jasieniak (CSIRO, Australia) for inspiration for the copper oxide synthesis and helpful comments on the paper, William Baumgardner and John Grazul for assistance with TEM imaging, and Dr. Maura Weathers for assistance with XRD. Device fabrication and testing was performed partly in the laboratory of Professor George Malliaras, while nanocrystal characterization was done using equipment in the Cornell Center for Materials Research (CCMR), Cornell Center for Nanoscale Systems (CNS), Cornell Nanoscale Science & Technology Facility (CNF), and the KAUST-Cornell Center for Energy and Sustainability. Y. F. Lim acknowledges a research fellowship from A*STAR, Singapore. J. J. Choi acknowledges support from NSF IGERT fellowship.
Publisher
Hindawi Publishing Corporation
Journal
Journal of Nanomaterials
ISSN
1687-4110
1687-4129
DOI
10.1155/2012/393160
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This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Except where otherwise noted, this item's license is described as This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.