Ultrathin Cu2O as an efficient inorganic hole transporting material for perovskite solar cells
Hedhili, Mohamed N.
Mohammed, Omar F.
KAUST DepartmentChemical Science Program
Imaging and Characterization Core Lab
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Laboratory of Nano Oxides for Sustainable Energy
Material Science and Engineering Program
Nanofabrication Core Lab
Physical Science and Engineering (PSE) Division
Safety & Facility
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Permanent link to this recordhttp://hdl.handle.net/10754/596968
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AbstractWe demonstrate that ultrathin P-type Cu2O thin films fabricated by a facile thermal oxidation method can serve as a promising hole-transporting material in perovskite solar cells. Following a two-step method, inorganic-organic hybrid perovskite solar cells were fabricated and a power conversion efficiency of 11.0% was achieved. We find that the thickness and properties of Cu2O layers must be precisely tuned in order to achieve the optimal solar cell performance. The good performance of such perovskite solar cells can be attributed to the unique properties of ultrathin Cu2O, including high hole mobility, good energy level alignment with CH3NH3PbI3, and longer lifetime of photo-excited carriers. Combining merits of low cost, facile synthesis, and high device performance, ultrathin Cu2O films fabricated via thermal oxidation hold promise for facilitating the developments of industrial-scale perovskite solar cells.
CitationUltrathin Cu2O as an efficient inorganic hole transporting material for perovskite solar cells 2016 Nanoscale
SponsorsThis work was supported by King Abdullah University of Science and Technology (KAUST). Dr. W. Yu acknowledges the support from the National Natural Science Foundation of China (NSFC 21404015).
PublisherRoyal Society of Chemistry (RSC)
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