Microbial Reverse-Electrodialysis Electrolysis and Chemical-Production Cell for H2 Production and CO2 Sequestration.
KAUST Grant NumberKUS-11-003-13
Online Publication Date2014-03-27
Print Publication Date2014-04-08
Permanent link to this recordhttp://hdl.handle.net/10754/596844
MetadataShow full item record
AbstractNatural mineral carbonation can be accelerated using acid and alkali solutions to enhance atmospheric CO2 sequestration, but the production of these solutions needs to be carbon-neutral. A microbial reverse-electrodialysis electrolysis and chemical-production cell (MRECC) was developed to produce these solutions and H2 gas using only renewable energy sources (organic matter and salinity gradient). Using acetate (0.82 g/L) as a fuel for microorganisms to generate electricity in the anode chamber (liquid volume of 28 mL), 0.45 mmol of acid and 1.09 mmol of alkali were produced at production efficiencies of 35% and 86%, respectively, along with 10 mL of H2 gas. Serpentine dissolution was enhanced 17-87-fold using the acid solution, with approximately 9 mL of CO2 absorbed and 4 mg of CO2 fixed as magnesium or calcium carbonates. The operational costs, based on mineral digging and grinding, and water pumping, were estimated to be only $\$$25/metric ton of CO2 fixed as insoluble carbonates. Considering the additional economic benefits of H2 generation and possible wastewater treatment, this method may be a cost-effective and environmentally friendly method for CO2 sequestration.
CitationZhu X, Hatzell MC, Logan BE (2014) Microbial Reverse-Electrodialysis Electrolysis and Chemical-Production Cell for H 2 Production and CO 2 Sequestration . Environ Sci Technol Lett 1: 231–235. Available: http://dx.doi.org/10.1021/ez500073q.
SponsorsThis research was supported by Award KUS-11-003-13 from the King Abdullah University of Science and Technology (KAUST). We thank Dr. George Alexander from the Department of Energy and Geo-Environmental Engineering of The Pennsylvania State University for providing natural minerals.
PublisherAmerican Chemical Society (ACS)
PubMed Central IDPMC3982931
CollectionsPublications Acknowledging KAUST Support
- Microbial electrolysis desalination and chemical-production cell for CO2 sequestration.
- Authors: Zhu X, Logan BE
- Issue date: 2014 May
- Direct electrolytic dissolution of silicate minerals for air CO2 mitigation and carbon-negative H2 production.
- Authors: Rau GH, Carroll SA, Bourcier WL, Singleton MJ, Smith MM, Aines RD
- Issue date: 2013 Jun 18
- Formate production from CO<sub>2</sub> electroreduction in a salinity-gradient energy intensified microbial electrochemical system.
- Authors: Tian Y, Li D, Liu G, Li C, Liu J, Wu J, Liu J, Feng Y
- Issue date: 2020 Oct 21
- Hydrogen production from continuous flow, microbial reverse-electrodialysis electrolysis cells treating fermentation wastewater.
- Authors: Watson VJ, Hatzell M, Logan BE
- Issue date: 2015 Nov
- Hydrogen production in microbial reverse-electrodialysis electrolysis cells using a substrate without buffer solution.
- Authors: Song YH, Hidayat S, Kim HK, Park JY
- Issue date: 2016 Jun