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    Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

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    Type
    Article
    Authors
    Bukhriakov, Konstantin
    Mugemana, Clement
    Vu, Khanh B.
    Rodionov, Valentin cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2015-09-23
    Online Publication Date
    2015-09-23
    Print Publication Date
    2015-10-02
    Permanent link to this record
    http://hdl.handle.net/10754/594090
    
    Metadata
    Show full item record
    Abstract
    An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.
    Citation
    Bukhryakov KV, Mugemana C, Vu KB, Rodionov VO (2015) Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer. Organic Letters 17: 4826–4829. Available: http://dx.doi.org/10.1021/acs.orglett.5b02388.
    Sponsors
    King Abdullah University of Science and Technology
    Publisher
    American Chemical Society (ACS)
    Journal
    Organic Letters
    DOI
    10.1021/acs.orglett.5b02388
    PubMed ID
    26397957
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.orglett.5b02388
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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