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dc.contributor.authorPérez-Manríquez, Liliana
dc.contributor.authorAburabie, Jamaliah
dc.contributor.authorNeelakanda, Pradeep
dc.contributor.authorPeinemann, Klaus-Viktor
dc.date.accessioned2016-01-19T13:20:56Z
dc.date.available2016-01-19T13:20:56Z
dc.date.issued2015-01
dc.identifier.citationPérez-Manríquez L, Aburabi’e J, Neelakanda P, Peinemann K-V (2015) Cross-linked PAN-based thin-film composite membranes for non-aqueous nanofiltration. Reactive and Functional Polymers 86: 243–247. Available: http://dx.doi.org/10.1016/j.reactfunctpolym.2014.09.015.
dc.identifier.issn1381-5148
dc.identifier.doi10.1016/j.reactfunctpolym.2014.09.015
dc.identifier.urihttp://hdl.handle.net/10754/594073
dc.description.abstractA new approach on the development of cross-linked PAN based thin film composite (TFC) membranes for non-aqueous application is presented in this work. Polypropylene backed neat PAN membranes fabricated by phase inversion process were cross-linked with hydrazine to get excellent solvent stability toward dimethylformamide (DMF). By interfacial polymerization a selective polyamide active layer was coated over the cross-linked PAN using N,N′-diamino piperazine (DAP) and trimesoyl chloride (TMC) as monomers. Permeation and molecular weight cut off (MWCO) experiments using various dyes were done to evaluate the performance of the membranes. Membranes developed by such method show excellent solvent stability toward DMF with a permeance of 1.7 L/m2 h bar and a molecular weight cut-off of less than 600 Da.
dc.description.sponsorshipThe authors acknowledge Madhavan Karunakaran for his contribution in the FTIR analysis. This work was supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherElsevier BV
dc.subjectInterfacial polymerization
dc.subjectNon-aqueous nanofiltration
dc.subjectPolyacrylonitrile
dc.titleCross-linked PAN-based thin-film composite membranes for non-aqueous nanofiltration
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentBioscience Program
dc.contributor.departmentChemical and Biological Engineering Program
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalReactive and Functional Polymers
kaust.personPerez Manriquez, Liliana
kaust.personAburabi'e, Jamaliah
kaust.personNeelakanda, Pradeep
kaust.personPeinemann, Klaus-Viktor


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