Cross-linked PAN-based thin-film composite membranes for non-aqueous nanofiltration
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical and Biological Engineering Program
Physical Sciences and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/594073
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AbstractA new approach on the development of cross-linked PAN based thin film composite (TFC) membranes for non-aqueous application is presented in this work. Polypropylene backed neat PAN membranes fabricated by phase inversion process were cross-linked with hydrazine to get excellent solvent stability toward dimethylformamide (DMF). By interfacial polymerization a selective polyamide active layer was coated over the cross-linked PAN using N,N′-diamino piperazine (DAP) and trimesoyl chloride (TMC) as monomers. Permeation and molecular weight cut off (MWCO) experiments using various dyes were done to evaluate the performance of the membranes. Membranes developed by such method show excellent solvent stability toward DMF with a permeance of 1.7 L/m2 h bar and a molecular weight cut-off of less than 600 Da.
CitationPérez-Manríquez L, Aburabi’e J, Neelakanda P, Peinemann K-V (2015) Cross-linked PAN-based thin-film composite membranes for non-aqueous nanofiltration. Reactive and Functional Polymers 86: 243–247. Available: http://dx.doi.org/10.1016/j.reactfunctpolym.2014.09.015.
SponsorsThe authors acknowledge Madhavan Karunakaran for his contribution in the FTIR analysis. This work was supported by King Abdullah University of Science and Technology (KAUST).
JournalReactive and Functional Polymers