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dc.contributor.authorAbdulHalim, Rasha
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorAl Kordi, Mohamed
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2016-01-10T10:04:54Z
dc.date.available2016-01-10T10:04:54Z
dc.date.issued2016-01-19
dc.identifier.citationSupramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs 2016 Crystal Growth & Design
dc.identifier.issn1528-7483
dc.identifier.issn1528-7505
dc.identifier.doi10.1021/acs.cgd.5b01307
dc.identifier.urihttp://hdl.handle.net/10754/593174
dc.description.abstractThree novel metal-organic frameworks (MOFs) were isolated upon reacting a heterofunctional ligand 4 (pyrimidin-5 yl)benzoic acid (4,5-pmbc) with mixed valence Cu(I,II) under solvothermal conditions. X-ray crystal structural analysis reveals that the first compound is a layered structure composed of one type of inorganic building block, dinuclear paddlewheel [Cu2(O2C–)4], which are linked through 4,5-pmbc ligands. The two other supramolecular isomers are composed of the same Cu(II) dinuclear paddlewheel and a dinuclear Cu2I2 cluster, which are linked via the 4,5-pmbc linkers to yield two different 3-periodic frameworks with underlying topologies related to lvt and nbo. The observed structural diversity in these structures is due to the distinct coordination modes of the two coordinating moieties (the carboxylate group on the phenyl ring and the N-donor atoms from the pyrimidine moiety).
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/10.1021/acs.cgd.5b01307
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal Growth & Design, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.cgd.5b01307.
dc.titleSupramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCrystal Growth & Design
dc.eprint.versionPost-print
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personAbdul Halim, Racha Ghassan
kaust.personShkurenko, Aleksander
kaust.personAl Kordi, Mohamed
kaust.personEddaoudi, Mohamed
dc.relation.issupplementedbyDOI:10.5517/cc1khc1g
dc.relation.issupplementedbyDOI:10.5517/cc1khc2h
dc.relation.issupplementedbyDOI:10.5517/cc1khc3j
refterms.dateFOA2017-01-04T00:00:00Z
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444725: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc1g. DOI: <a href="https://doi.org/10.5517/cc1khc1g">10.5517/cc1khc1g</a> HANDLE: <a href="http://hdl.handle.net/10754/624490">10754/624490</a></li><li><i>[Dataset]</i> <br/> AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444726: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc2h. DOI: <a href="https://doi.org/10.5517/cc1khc2h">10.5517/cc1khc2h</a> HANDLE: <a href="http://hdl.handle.net/10754/624491">10754/624491</a></li><li><i>[Dataset]</i> <br/> AbdulHalim, R. G., Shkurenko, A., Alkordi, M. H., & Eddaoudi, M. (2016). CCDC 1444727: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1khc3j. DOI: <a href="https://doi.org/10.5517/cc1khc3j">10.5517/cc1khc3j</a> HANDLE: <a href="http://hdl.handle.net/10754/624492">10754/624492</a></li></ul>
dc.date.published-online2016-01-19
dc.date.published-print2016-02-03


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