CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand
Type
ArticleAuthors
Pasha, Fahran AhmadBendjeriou-Sedjerari, Anissa
Abou-Hamad, Edy
Huang, Kuo-Wei
Basset, Jean-Marie
KAUST Department
KAUST Catalysis Center (KCC)Date
2016-01-04Permanent link to this record
http://hdl.handle.net/10754/593138Metadata
Show full item recordAbstract
Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.Citation
CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand 2016 Chem. Commun.Publisher
Royal Society of Chemistry (RSC)Journal
Chem. Commun.ISSN
1359-73451364-548X