CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand
Type
ArticleAuthors
Pasha, Fahran AhmadBendjeriou-Sedjerari, Anissa
Abou-Hamad, Edy

Huang, Kuo-Wei

Basset, Jean-Marie

KAUST Department
Chemical Science ProgramHomogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2016Permanent link to this record
http://hdl.handle.net/10754/593138
Metadata
Show full item recordAbstract
Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.Citation
CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand 2016 Chem. Commun.Publisher
Royal Society of Chemistry (RSC)Journal
Chemical CommunicationsPubMed ID
26750777Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC08821Fae974a485f413a2113503eed53cd6c53
10.1039/C5CC08821F
Scopus Count
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