• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguideTheses and Dissertations LibguideSubmit an Item

    Statistics

    Display statistics

    CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    c5cc08821f.pdf
    Size:
    1006.Kb
    Format:
    PDF
    Description:
    Accepted Manuscript
    Download
    Thumbnail
    Name:
    c5cc08821f1.pdf
    Size:
    415.5Kb
    Format:
    PDF
    Description:
    Supplemental files
    Download
    Type
    Article
    Authors
    Pasha, Fahran Ahmad
    Bendjeriou-Sedjerari, Anissa
    Abou-Hamad, Edy cc
    Huang, Kuo-Wei cc
    Basset, Jean-Marie cc
    KAUST Department
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2016
    Permanent link to this record
    http://hdl.handle.net/10754/593138
    
    Metadata
    Show full item record
    Abstract
    Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.
    Citation
    CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand 2016 Chem. Commun.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/C5CC08821F
    PubMed ID
    26750777
    Additional Links
    http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC08821F
    ae974a485f413a2113503eed53cd6c53
    10.1039/C5CC08821F
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

    entitlement

    Related articles

    • Bipodal surface organometallic complexes with surface N-donor ligands and application to the catalytic cleavage of C-H and C-C bonds in n-butane.
    • Authors: Bendjeriou-Sedjerari A, Azzi JM, Abou-Hamad E, Anjum DH, Pasha FA, Huang KW, Emsley L, Basset JM
    • Issue date: 2013 Nov 27
    • Tungsten(VI) Carbyne/Bis(carbene) Tautomerization Enabled by N-Donor SBA15 Surface Ligands: A Solid-State NMR and DFT Study.
    • Authors: Bendjeriou-Sedjerari A, Sofack-Kreutzer J, Minenkov Y, Abou-Hamad E, Hamzaoui B, Werghi B, Anjum DH, Cavallo L, Huang KW, Basset JM
    • Issue date: 2016 Sep 5
    • Molecular understanding of the formation of surface zirconium hydrides upon thermal treatment under hydrogen of [([triple bond]SiO)Zr(CH2tBu)3] by using advanced solid-state NMR techniques.
    • Authors: Rataboul F, Baudouin A, Thieuleux C, Veyre L, Copéret C, Thivolle-Cazat J, Basset JM, Lesage A, Emsley L
    • Issue date: 2004 Oct 6
    • Well-defined surface imido amido tantalum(v) species from ammonia and silica-supported tantalum hydrides.
    • Authors: Avenier P, Lesage A, Taoufik M, Baudouin A, Mallmann AD, Fiddy S, Vautier M, Veyre L, Basset JM, Emsley L, Quadrelli EA
    • Issue date: 2007 Jan 10
    • Cationic zirconium hydrides supported by an NNNN-type macrocyclic ligand: synthesis, structure, and reactivity.
    • Authors: Kulinna H, Spaniol TP, Maron L, Okuda J
    • Issue date: 2012 Nov 19
    DSpace software copyright © 2002-2023  DuraSpace
    Quick Guide | Contact Us | KAUST University Library
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.