By combining computational aided design with synthetic chemistry, we are able to identify core 2D polyaromatic small molecule templates with the necessary optoelectronic properties for p- and n-type materials. By judicious selection of the functional groups, we can tune the physical properties of the material making them amenable to solution and vacuum deposition. In addition to solubility, we observe that the functional group can influence the thin film molecular packing. By developing structure-property relationships (SPRs) for these families of compounds we observe that some compounds are better suited for use in organic solar cells, while others, varying only slightly in structure, are favoured in organic field effect transistor devices. We also find that the processing conditions can have a dramatic impact on molecular packing (i.e. 1D vs 2D polymorphism) and charge mobility; this has implications for material and device long term stability. We have developed small molecule p- and n-type materials for organic solar cells with efficiencies exceeding 2%. Subtle variations in the functional groups of these materials produces p- and ntype materials with mobilities higher than 0.3 cm2/Vs. We are also interested in using our SPR approach to develop materials for sensor and bioelectronic applications.
Alhadidi, A.; Al-Taweel, H.; Al-Dakhil, A.; Al-Zahrani, A.; Alkhazraji, E.; Alsunaidi, M. A.(2015 IEEE Jordan Conference on Applied Electrical Engineering and Computing Technologies (AEECT), Institute of Electrical and Electronics Engineers (IEEE), 2015-11)[Conference Paper]
We experimentally demonstrate the effect of depositing gold-coated ZnO nanoparticles on the surface of GaN multi-quantum well LED structures. We show that this method can significantly increase the amount of extracted light.
Ekenna, Chinwe; Uwacu, Diane; Thomas, Shawna; Amato, Nancy M.(2015 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS), Institute of Electrical and Electronics Engineers (IEEE), 2015-09)[Conference Paper]
The focus of this paper is to optimize the solar energy utilization in the water desalination process. Due to variable nature of solar energy, new system design is needed to address this challenge. Here, reverse osmosis units, as the electrical loads, are considered as an ON/OFF units to track these solar energy variations. Reverse osmosis units are different in sizes and numbers. Various combinations of reverse osmosis units in size and capacity provide different water desalination system performances. To assess each scenario of reverse osmosis units, the total capital cost and operation and maintenance (O&M) cost are considered. The implemented optimization algorithm search all of the possible scenarios to find the best solution. This paper deploys the solar irradiance data which is provided from west coast (Red Sea) of Saudi Arabia for model construction and optimization algorithm implementation.
Watanabe, Hirotatsu; Shanbhogue, Santosh J.; Ghoniem, Ahmed F.(Volume 4B: Combustion, Fuels and Emissions, ASME International, 2015-06-15)[Conference Paper]
Premixed CH4/O2/CO2 flames (oxy-flames) and CH4/air flames (air-flames) were experimentally studied in a swirl-stabilized combustor. For comparing oxy and air flames, the same equivalence ratio and adiabatic flame temperature were used. CO2 dilution was adjusted to attain the same adiabatic temperature for the oxy-flame and the corresponding air-flame while keeping the equivalence ratio and Reynolds number (=20,000) the same. For high equivalence ratios, we observed flames stabilized along the inner and outer shear layers of the swirling flow and sudden expansion, respectively, in both flames. However, one notable difference between the two flames appears as the equivalence ratio reaches 0.60. At this point, the outer shear layer flame disappears in the air-flame while it persists in the oxy-flame, despite the lower burning velocity of the oxy-flame. Prior PIV measurements (Ref. 9) showed that the strains along the outer shear layer are higher than along the inner shear layer. Therefore, the extinction strain rates in both flames were calculated using a counter-flow premixed twin flame configuration. Calculations at the equivalence ratio of 0.60 show that the extinction strain rate is higher in the oxy than in the air flame, which help explain why it persists on the outer shear layer with higher strain rate. It is likely that extinction strain rates contribute to the oxy-flame stabilization when air flame extinguish in the outer shear layer. However, the trend reverses at higher equivalence ratio, and the cross point of the extinction strain rate appears at equivalence ratio of 0.64.
ul Hasan Khan, Ayaz; Al-Mouhamed, Mayez; Firdaus, Lutfi A.(2015 IEEE/ACIS 16th International Conference on Software Engineering, Artificial Intelligence, Networking and Parallel/Distributed Computing (SNPD), Institute of Electrical and Electronics Engineers (IEEE), 2015-06)[Conference Paper]
Al-Habob, Ahmed A.; Sorour, Sameh; Aboutorab, Neda; Sadeghi, Parastoo(2015 IEEE International Conference on Communications (ICC), Institute of Electrical and Electronics Engineers (IEEE), 2015-06)[Conference Paper]
ul Hasan Khan, Ayaz; Al-Mouhamed, Mayez; Fatayer, Allam(2015 IEEE/ACIS 16th International Conference on Software Engineering, Artificial Intelligence, Networking and Parallel/Distributed Computing (SNPD), Institute of Electrical and Electronics Engineers (IEEE), 2015-06)[Conference Paper]
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