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dc.contributor.authorLee, Young-Ho
dc.contributor.authorPark, Jung-Hyun
dc.contributor.authorShin, Chae-Ho
dc.date.accessioned2015-10-12T05:34:38Z
dc.date.available2015-10-12T05:34:38Z
dc.date.issued2015-09-27
dc.identifier.citationLee, Y.-H., Park, J.-H., & Shin, C.-H. (2016). Physicochemical properties of manganese dioxide synthesized using C2–C5 alcohols as reducing agents and their catalytic activities for CO oxidation. Catalysis Today, 265, 7–13. doi:10.1016/j.cattod.2015.08.032
dc.identifier.issn0920-5861
dc.identifier.doi10.1016/j.cattod.2015.08.032
dc.identifier.urihttp://hdl.handle.net/10754/579545
dc.description.abstractMnO2 catalysts were synthesized in an aqueous solution of KMnO4 and C2–C5 alcohols using a simple redox method at room temperature. The crystalline structure of all samples was δ-MnO2 after being calcined at 300 °C. However, other physicochemical properties of the samples varied depending on the symmetry of the alcohols used. For the catalytic oxidation of CO, MnO2 catalysts prepared with 1° alcohols performed better than the samples prepared in 2° alcohols. Catalytic activities were correlated to the quantity of labile oxygen species of the catalysts. In CO-TPD analysis, the relative area of desorbed radical dotCO2, which is the product of the reaction between adsorbed CO and lattice oxygen species, becomes larger for MnO2 prepared with 1° alcohols than with 2° alcohols. These results were primarily resulted from the innate hydrogen dissociation behavior of alcohol in solution. The pKa was found to be an important factor in determining the physicochemical properties and catalytic activity toward CO oxidation of MnO2.
dc.language.isoen
dc.publisherElsevier BV
dc.relation.urlhttp://www.sciencedirect.com/science/article/pii/S092058611500512X
dc.subjectMnO2
dc.subjectAlcohol
dc.subjectpKa
dc.subjectLattice oxygen species
dc.subjectCO oxidation
dc.titlePhysicochemical properties of manganese dioxide synthesized using C2–C5 alcohols as reducing agents and their catalytic activities for CO oxidation
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCatalysis Today
dc.eprint.versionPost-print
dc.contributor.institutionChemical Engineering, Chungbuk National University, Cheongju 28644, Republic of Korea
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personPark, Jung-Hyun
refterms.dateFOA2017-09-26T00:00:00Z
dc.date.published-online2015-09-27
dc.date.published-print2016-05


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