Show simple item record

dc.contributor.authorMaculan, Giacomo
dc.contributor.authorSheikh, Arif D.
dc.contributor.authorAbdelhady, Ahmed L.
dc.contributor.authorSaidaminov, Makhsud I.
dc.contributor.authorHaque, Mohammed
dc.contributor.authorBanavoth, Murali
dc.contributor.authorAlarousu, Erkki
dc.contributor.authorMohammed, Omar F.
dc.contributor.authorWu, Tao
dc.contributor.authorBakr, Osman
dc.date.accessioned2015-09-09T05:38:16Z
dc.date.available2015-09-09T05:38:16Z
dc.date.issued2015-09-02
dc.identifier.citationCH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector 2015:150902175316001 The Journal of Physical Chemistry Letters
dc.identifier.issn1948-7185
dc.identifier.pmid26722870
dc.identifier.doi10.1021/acs.jpclett.5b01666
dc.identifier.urihttp://hdl.handle.net/10754/576968
dc.description.abstractSingle crystals of hybrid perovskites have shown remarkably improved physical properties compared to their polycrystalline film counterparts, underscoring their importance in the further development of advanced semiconductor devices. Here we present a new method of sizeable CH3NH3PbCl3 single crystal growth based on retrograde solubility behavior of hybrid perovskites. We show, for the first time, the energy band structure, charge-carrier recombination and transport properties of single crystal CH3NH3PbCl3. The chloride-based perovskite crystals exhibit trap-state density, charge carriers concentration, mobility and diffusion length comparable with the best quality crystals of methylammonium lead iodide or bromide perovskites reported so far. The high quality of the crystal along with its suitable optical bandgap enabled us to design and build an efficient visible-blind UV-photodetector, demonstrating the potential of this material to be employed in optoelectronic applications.
dc.language.isoen
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/10.1021/acs.jpclett.5b01666
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.jpclett.5b01666.
dc.titleCH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector
dc.typeArticle
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentMaterials Science and Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalThe Journal of Physical Chemistry Letters
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, Faculty of Science, Mansoura University, Mansoura, 35516, Egypt
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personMaculan, Giacomo
kaust.personSheikh, Arif D.
kaust.personAbdelhady, Ahmed L.
kaust.personSaidaminov, Makhsud I.
kaust.personHaque, Mohammed
kaust.personBanavoth, Murali
kaust.personAlarousu, Erkki
kaust.personMohammed, Omar F.
kaust.personWu, Tao
kaust.personBakr, Osman
refterms.dateFOA2016-09-02T00:00:00Z


Files in this item

Thumbnail
Name:
acs2Ejpclett2E5b01666.pdf
Size:
957.9Kb
Format:
PDF
Description:
Accepted Manuscript

This item appears in the following Collection(s)

Show simple item record