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dc.contributor.authorCallens, Emmanuel
dc.contributor.authorRiache, Nassima
dc.contributor.authorTalbi, Karima
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-30T11:18:15Z
dc.date.available2015-08-30T11:18:15Z
dc.date.issued2015
dc.identifier.citationSimple addition of silica to an alkane solution of Wilkinson WMe6 or Schrock W alkylidyne complex give active complex for saturated and unsaturated hydrocarbons metathesis 2015 Chem. Commun.
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.pmid26340517
dc.identifier.doi10.1039/C5CC05276A
dc.identifier.urihttp://hdl.handle.net/10754/576051
dc.description.abstractAddition of PDA silica to a solution of the Wilkinson WMe6 as well as the Schrock W neopentilidyne tris neopentyl complex catalyzes linear or cyclic alkanes to produce respectively a distribution of linear alkanes from methane up to triacontane or a mixture of cyclic and macrocyclic hydrocarbons. This single catalytic system transforms also linear α-olefins into higher and lower homologues via isomerization/metathesis mechanism (ISOMET). This complex is also efficient towards functionalized olefins. Unsaturated fatty acid esters (FAEs) are converted into diesters corresponding to self-metathesis products.
dc.language.isoen
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC05276A
dc.rightsArchived with thanks to Chem. Commun.
dc.titleSimple addition of silica to an alkane solution of Wilkinson WMe6 or Schrock W alkylidyne complex give active complex for saturated and unsaturated hydrocarbons metathesis
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentCompetitive Research Funds
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentOCRF- Special Academic Partnership
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemical Communications
dc.eprint.versionPost-print
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)
kaust.personCallens, Emmanuel
kaust.personRiache, Nassima
kaust.personTalbi, Karima
kaust.personBasset, Jean-Marie
refterms.dateFOA2016-08-24T00:00:00Z


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