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    Phosphazene-promoted anionic polymerization

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    Type
    Article
    Authors
    Zhao, Junpeng cc
    Hadjichristidis, Nikos cc
    Gnanou, Yves cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Polymer Synthesis Laboratory
    Date
    2014-01
    Permanent link to this record
    http://hdl.handle.net/10754/575702
    
    Metadata
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    Abstract
    In the recent surge of metal-free polymerization techniques, phosphazene bases have shown their remarkable potential as organic promoters/catalysts for the anionic polymerization of various types of monomers. By complexation with the counterion (e.g. proton or lithium cation), phosphazene base significantly improve the nucleophilicity of the initiator/chain-end resulting in rapid and usually controlled anionic/quasi-anionic polymerization. In this review, we will introduce the general mechanism, i.e. in situ activation (of initiating sites) and polymerization, and summarize the applications of such a mechanism on macromolecular engineering toward functionalized polymers, block copolymers and complex macromolecular architectures.
    Publisher
    Industrial Chemistry Research Institute
    Journal
    Polimery
    DOI
    10.14314/polimery.2014.049
    ae974a485f413a2113503eed53cd6c53
    10.14314/polimery.2014.049
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Science Program; KAUST Catalysis Center (KCC)

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