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    Magnetically recoverable nanocatalysts

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    Type
    Article
    Authors
    Polshettiwar, Vivek cc
    Luque, Rafael L.
    Fihri, Aziz
    Zhu, Haibo
    Bouhrara, Mohamed
    Basset, Jean-Marie cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2011-05-11
    Permanent link to this record
    http://hdl.handle.net/10754/565992
    
    Metadata
    Show full item record
    Abstract
    A broad overview on magnetically recoverable nanocatalysts is presented and the use of magnetic nanomaterials as catalysts is discussed. Magnetic materials are used as organocatalysts and their applications range to challenging reactions, such as hydroformylation and olefin metathesis. Magnetic nanomaterials are also being used in environmental applications, such as for photo- and biocatalysis and for the adsorption and removal of pollutants from air and water. These materials show great promise as enantioselective catalysts, which are used extensively for the synthesis of medicines, drugs, and other bioactive molecules. By functionalizing these materials using chiral ligands, a series of chiral nanocatalysts can be designed, offering great potential to reuse these otherwise expensive catalyst systems. Characterization of magnetic catalysts is often a challenging task, and NMR characterization of these catalysts is difficult because the magnetic nature of the materials interferes with the magnetic field of the spectrometer.
    Citation
    Polshettiwar, V., Luque, R., Fihri, A., Zhu, H., Bouhrara, M., & Basset, J.-M. (2011). Magnetically Recoverable Nanocatalysts. Chemical Reviews, 111(5), 3036–3075. doi:10.1021/cr100230z
    Sponsors
    We gratefully acknowledge funding and support from King Abdullah University of Science and Technology (KAUST). Thanks are also due to the KAUST communication department for designing several images for this Review.
    Publisher
    American Chemical Society (ACS)
    Journal
    Chemical Reviews
    DOI
    10.1021/cr100230z
    PubMed ID
    21401074
    ae974a485f413a2113503eed53cd6c53
    10.1021/cr100230z
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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