Hydrogen permeation properties of Pd-coated V89.8Cr 10Y0.2 alloy membrane using WGS reaction gases
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Permanent link to this recordhttp://hdl.handle.net/10754/564711
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AbstractThe influence of co-existing gases on the hydrogen permeation was studied through a Pd-coated V89.8Cr10Y0.2 alloy membrane. Preliminary hydrogen permeation experiments have been confirmed that hydrogen flux was 6.26 ml/min/cm2 for a Pd-coated V 89.8Cr10Y0.2 alloy membrane (thick: 0.5 mm) using pure hydrogen as feed gas. Also, the hydrogen permeation flux decreased with decrease of hydrogen partial pressure at constant pressure when H 2/CO2 and H2/CO2/H2S mixture applied as feed gas respectively and permeation fluxes were satisfied with Sievert's law in different feed conditions. It was found from XRD and SEM results after permeation test that the Pd-coated V89.8Cr 10Y0.2 alloy membrane had good stability and durability for various mixture feeding conditions. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
SponsorsThis work was supported by Energy & Resource R&D program (2011201020005B) under the Ministry of Knowledge Economy, Republic of Korea. The authors would like to thank Dr. Eric Fleury for his experimental help in the synthesis of alloy membrane at the Center for High Temperature Energy Materials of the Korean Institute of Science and Technology (KIST).