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dc.contributor.authorAnneser, Markus R.
dc.contributor.authorHaslinger, Stefan
dc.contributor.authorPöthig, Alexander
dc.contributor.authorCokoja, Mirza
dc.contributor.authorBasset, Jean-Marie
dc.contributor.authorKühn, Fritz
dc.date.accessioned2015-08-03T12:34:00Z
dc.date.available2015-08-03T12:34:00Z
dc.date.issued2015-04-20
dc.identifier.issn00201669
dc.identifier.pmid25843109
dc.identifier.doi10.1021/ic503043h
dc.identifier.urihttp://hdl.handle.net/10754/564145
dc.description.abstractAn iron(II) complex with a cyclic tetradentate ligand containing four N-heterocyclic carbenes was synthesized and characterized by means of NMR and IR spectroscopies, as well as by single-crystal X-ray structure analysis. The iron center exhibits an octahedral coordination geometry with two acetonitrile ligands in axial positions, showing structural analogies with porphyrine-ligated iron complexes. The acetonitrile ligands can readily be substituted by other ligands, for instance, dimethyl sulfoxide, carbon monoxide, and nitric oxide. Cyclic voltammetry was used to examine the electronic properties of the synthesized compounds. © 2015 American Chemical Society.
dc.description.sponsorshipM.R.A. and S.H. gratefully acknowledge support by the TUM Graduate School. This project was supported through a collaboration with the King Abdullah University of Saudi-Arabia (Grant No. KSA-00069/UKC0020).
dc.publisherAmerican Chemical Society (ACS)
dc.titleSynthesis and characterization of an iron complex bearing a cyclic tetra-N-heterocyclic carbene ligand: An artifical heme analogue?
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.identifier.journalInorganic Chemistry
dc.contributor.institutionDepartment of Inorganic Chemistry/Molecular Catalysis, Catalysis Research Center, Technische Universität München (TUM), Lichtenbergstrasse 4Garching bei München, Germany
kaust.personBasset, Jean-Marie
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 963848: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11byw6
dc.relation.isSupplementedByDOI:10.5517/cc11byw6
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624263
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036601: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13snr9
dc.relation.isSupplementedByDOI:10.5517/cc13snr9
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624390
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036602: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13snsb
dc.relation.isSupplementedByDOI:10.5517/cc13snsb
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624391
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036603: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13sntc
dc.relation.isSupplementedByDOI:10.5517/cc13sntc
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624392


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