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dc.contributor.authorAnneser, Markus R.*
dc.contributor.authorHaslinger, Stefan*
dc.contributor.authorPöthig, Alexander*
dc.contributor.authorCokoja, Mirza*
dc.contributor.authorBasset, Jean-Marie*
dc.contributor.authorKühn, Fritz*
dc.date.accessioned2015-08-03T12:34:00Zen
dc.date.available2015-08-03T12:34:00Zen
dc.date.issued2015-04-20en
dc.identifier.issn00201669en
dc.identifier.pmid25843109
dc.identifier.doi10.1021/ic503043hen
dc.identifier.urihttp://hdl.handle.net/10754/564145en
dc.description.abstractAn iron(II) complex with a cyclic tetradentate ligand containing four N-heterocyclic carbenes was synthesized and characterized by means of NMR and IR spectroscopies, as well as by single-crystal X-ray structure analysis. The iron center exhibits an octahedral coordination geometry with two acetonitrile ligands in axial positions, showing structural analogies with porphyrine-ligated iron complexes. The acetonitrile ligands can readily be substituted by other ligands, for instance, dimethyl sulfoxide, carbon monoxide, and nitric oxide. Cyclic voltammetry was used to examine the electronic properties of the synthesized compounds. © 2015 American Chemical Society.en
dc.description.sponsorshipM.R.A. and S.H. gratefully acknowledge support by the TUM Graduate School. This project was supported through a collaboration with the King Abdullah University of Saudi-Arabia (Grant No. KSA-00069/UKC0020).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleSynthesis and characterization of an iron complex bearing a cyclic tetra-N-heterocyclic carbene ligand: An artifical heme analogue?en
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)*
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division*
dc.contributor.departmentChemical Science Program*
dc.identifier.journalInorganic Chemistryen
dc.contributor.institutionDepartment of Inorganic Chemistry/Molecular Catalysis, Catalysis Research Center, Technische Universität München (TUM), Lichtenbergstrasse 4Garching bei München, Germany*
kaust.authorBasset, Jean-Marie*
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 963848: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11byw6en
dc.relation.isSupplementedByDOI:10.5517/cc11byw6en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624263en
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036601: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13snr9en
dc.relation.isSupplementedByDOI:10.5517/cc13snr9en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624390en
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036602: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13snsben
dc.relation.isSupplementedByDOI:10.5517/cc13snsben
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624391en
dc.relation.isSupplementedByAnneser, M. R., Haslinger, S., Pöthig, A., Cokoja, M., Basset, J.-M., & Kühn, F. E. (2015). CCDC 1036603: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13sntcen
dc.relation.isSupplementedByDOI:10.5517/cc13sntcen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624392en


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