Effect of Support on Metathesis of n-Decane: Drastic Improvement in Alkane Metathesis with WMe5 Linked to Silica-Alumina
KAUST DepartmentAli I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Online Publication Date2015-03-11
Print Publication Date2015-04-13
Permanent link to this recordhttp://hdl.handle.net/10754/564103
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Abstract[WMe6] (1) supported on the surface of SiO2-Al2O3(500) (2) has been extensively characterized by solid-state NMR spectroscopy, elemental analysis, and gas quantification, which clearly reveal the formation of a mixture of monopodal and bipodal species with the migration of methyl from W to Al. The supported species SiO2-Al2O3(500) (2) transformed at 120°C into two types of carbynic centers, one of which is cationic and the other neutral. These species are very efficient for the metathesis of n-decane. Comparison with already-synthesized neutral bipodal tungsten indicates that the high increase in activity is due to the cationic character of the grafted tungsten.
SponsorsThe authors acknowledge the KAUST Nuclear Magnetic Resonance Core Lab and technical assistance from Dr. Kazuo Yamauchi. The authors also thank Professor Lyndon Emsley, Dr. Emmanuel Callens, and Dr. Nassima Riache for fruitful discussions. This work was supported by funds from King Abdullah University of Science and Technology.
JournalChemistry - A European Journal