Silica-supported tungsten carbynes (≡SiO)xW(≡CH)(Me)y (x = 1, y = 2; X = 2, y = 1): New efficient catalysts for alkyne cyclotrimerization
KAUST DepartmentAdvanced Nanofabrication, Imaging and Characterization Core Lab
Chemical Science Program
Imaging and Characterization Core Lab
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Online Publication Date2015-02-02
Print Publication Date2015-02-23
Permanent link to this recordhttp://hdl.handle.net/10754/564064
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AbstractThe activity of silica-supported tungsten carbyne complexes (≡SiO)xW(≡CH)(Me)y (x = 1, y = 2; x = 2, y = 1) toward alkynes is reported. We found that they are efficient precatalysts for terminal alkyne cyclotrimerization with high TONs. We also demonstrate that this catalyst species is active for alkyne cyclotrimerization without the formation of significant alkyne metathesis products. Additional DFT calculations highlight the importance of the W coordination sphere in supporting this experimental behavior.
CitationRiache, N., Dery, A., Callens, E., Poater, A., Samantaray, M., Dey, R., … Basset, J.-M. (2015). Silica-Supported Tungsten Carbynes (≡SiO)xW(≡CH)(Me)y (x = 1, y = 2; x = 2, y = 1): New Efficient Catalysts for Alkyne Cyclotrimerization. Organometallics, 34(4), 690–695. doi:10.1021/om500684e
SponsorsResearch reported in this publication was supported by the King Abdullah University of Science and Technology. A.P. thanks the Spanish MINECO for a Ramon y Cajal contract (RYC-2009-05226) and the European Commission for a Career Integration Grant (CIG09-GA-2011-293900).
PublisherAmerican Chemical Society (ACS)