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dc.contributor.authorAlmaythalony, Bassem
dc.contributor.authorShekhah, Osama
dc.contributor.authorSwaidan, Raja
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorPinnau, Ingo
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2015-08-03T12:29:56Z
dc.date.available2015-08-03T12:29:56Z
dc.date.issued2015-01-28
dc.identifier.citationAl-Maythalony, B. A., Shekhah, O., Swaidan, R., Belmabkhout, Y., Pinnau, I., & Eddaoudi, M. (2015). Quest for Anionic MOF Membranes: Continuous sod-ZMOF Membrane with CO2 Adsorption-Driven Selectivity. Journal of the American Chemical Society, 137(5), 1754–1757. doi:10.1021/ja511495j
dc.identifier.issn00027863
dc.identifier.pmid25580818
dc.identifier.doi10.1021/ja511495j
dc.identifier.urihttp://hdl.handle.net/10754/564052
dc.description.abstractWe report the fabrication of the first continuous zeolite-like metal-organic framework (ZMOF) thin-film membrane. A pure phase sod-ZMOF, sodalite topology, membrane was grown and supported on a porous alumina substrate using a solvothermal crystallization method. The absence of pinhole defects in the film was confirmed and supported by the occurrence of quantifiable time-lags, for all studied gases, during constant volume/variable pressure permeation tests. For both pure and mixed gas feeds, the sod-ZMOF-1 membrane exhibits favorable permeation selectivity toward carbon dioxide over relevant industrial gases such as H2, N2, and CH4, and it is mainly governed by favorable CO2 adsorption.
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
dc.publisherAmerican Chemical Society (ACS)
dc.titleQuest for anionic MOF membranes: Continuous sod -ZMOF membrane with Co2 adsorption-driven selectivity
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
kaust.personShekhah, Osama
kaust.personSwaidan, Raja
kaust.personBelmabkhout, Youssef
kaust.personPinnau, Ingo
kaust.personEddaoudi, Mohamed
kaust.personAlmaythalony, Bassem
dc.date.published-online2015-01-28
dc.date.published-print2015-02-11


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