KAUST DepartmentChemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Online Publication Date2015-01-27
Print Publication Date2015-02-06
Permanent link to this recordhttp://hdl.handle.net/10754/564046
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AbstractAlkoxy-wrapped N-annulated perylene (NP) was synthesized and used as a rigid and coplanar π-linker for three push-pull type metal-free sensitizers QB1-QB3. Their optical and electrochemical properties were tuned by varying the structure of acceptor. These new dyes were applied in Co(II)/(III) based dye-sensitized solar cells, and power conversion efficiency up to 6.95% was achieved, indicating that NP could be used as a new building block for the design of high-performance sensitizers in the future.
CitationQi, Q., Wang, X., Fan, L., Zheng, B., Zeng, W., Luo, J., … Wu, J. (2015). N-Annulated Perylene-Based Push–Pull-Type Sensitizers. Organic Letters, 17(3), 724–727. doi:10.1021/ol503749f
SponsorsJ.W. and Q.W. acknowledge financial support from MOE Tier 2 grant (MOE2011-T2-2-130), A*STAR-DST joint grant (IMRE/14-2C0239), and IMRE core funding (IMRE/13-1C0205). K.-W.H. acknowledges financial support from KAUST.
PublisherAmerican Chemical Society (ACS)