Chalcogenophene comonomer comparison in small band gap diketopyrrolopyrrole-based conjugated polymers for high-performing field-effect transistors and organic solar cells
AuthorsAshraf, Raja Shahid
Schroeder, Bob C.
Nielsen, Christian Bergenstof
KAUST DepartmentChemical Science Program
KAUST Solar Center (KSC)
Physical Science and Engineering (PSE) Division
Online Publication Date2015-01-14
Print Publication Date2015-01-28
Permanent link to this recordhttp://hdl.handle.net/10754/564023
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AbstractThe design, synthesis, and characterization of a series of diketopyrrolopyrrole-based copolymers with different chalcogenophene comonomers (thiophene, selenophene, and tellurophene) for use in field-effect transistors and organic photovoltaic devices are reported. The effect of the heteroatom substitution on the optical, electrochemical, and photovoltaic properties and charge carrier mobilities of these polymers is discussed. The results indicate that by increasing the size of the chalcogen atom (S < Se < Te), polymer band gaps are narrowed mainly due to LUMO energy level stabilization. In addition, the larger heteroatomic size also increases intermolecular heteroatom-heteroatom interactions facilitating the formation of polymer aggregates leading to enhanced field-effect mobilities of 1.6 cm2/(V s). Bulk heterojunction solar cells based on the chalcogenophene polymer series blended with fullerene derivatives show good photovoltaic properties, with power conversion efficiencies ranging from 7.1-8.8%. A high photoresponse in the near-infrared (NIR) region with excellent photocurrents above 20 mA cm-2 was achieved for all polymers, making these highly efficient low band gap polymers promising candidates for use in tandem solar cells. (Graph Presented).
CitationAshraf, R. S., Meager, I., Nikolka, M., Kirkus, M., Planells, M., Schroeder, B. C., … McCulloch, I. (2015). Chalcogenophene Comonomer Comparison in Small Band Gap Diketopyrrolopyrrole-Based Conjugated Polymers for High-Performing Field-Effect Transistors and Organic Solar Cells. Journal of the American Chemical Society, 137(3), 1314–1321. doi:10.1021/ja511984q
SponsorsThis work was carried out primarily with funding and supports from the X10D Project (EC 287818) and The Leventis Foundation with support from EPSRC (EP/G037515/1 and EP/L016702/1). M.K. acknowledges support from Nano-matcell Project (EU 308997), and M.P. acknowledges support from the Artesun Project (EU 604397).
PublisherAmerican Chemical Society (ACS)