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dc.contributor.authorHamzaoui, Bilel
dc.contributor.authorEl Eter, Mohamad
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorChen, Yin
dc.contributor.authorPelletier, Jeremie
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-03T12:22:50Z
dc.date.available2015-08-03T12:22:50Z
dc.date.issued2015-01-13
dc.identifier.issn09476539
dc.identifier.pmid25585538
dc.identifier.doi10.1002/chem.201405788
dc.identifier.urihttp://hdl.handle.net/10754/564007
dc.description.abstractThe silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
dc.description.sponsorshipThe authors wish to thank the King Abdullah University of Science and Technology for continuous support.
dc.publisherWiley
dc.subjectAzazirconacyclopropanes
dc.subjectHydrogenation
dc.subjectMonohydrides
dc.subjectOrganometallic chemistry
dc.subjectSurface chemistry
dc.titleWell-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - A European Journal
kaust.personEl Eter, Mohamad
kaust.personAbou-Hamad, Edy
kaust.personChen, Yin
kaust.personPelletier, Jeremie
kaust.personBasset, Jean-Marie
kaust.personHamzaoui, Bilel
dc.date.published-online2015-01-13
dc.date.published-print2015-03-09


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