A rationally designed amino-borane complex in a metal organic framework: A novel reusable hydrogen storage and size-selective reduction material

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Type
Article
Authors
Wang, Xinbo
Xie, Linhua cc
Huang, Kuo-Wei cc
Lai, Zhiping cc
KAUST Department
Physical Sciences and Engineering (PSE) Division
Chemical and Biological Engineering Program
Advanced Membranes and Porous Materials Research Center
Chemical Science Program
KAUST Catalysis Center (KCC)
HCL
Date
2015

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Abstract
A novel amino-borane complex inside a stable metal organic framework was synthesized for the first time. It releases hydrogen at a temperature of 78 °C with no volatile contaminants and can be well reused. Its application as a size-selective reduction material in organic synthesis was also demonstrated. © The Royal Society of Chemistry 2015.
Sponsors
Financial support from KAUST Competitive Grant URF/1/1378 and Baseline fund BAS/1/1375 is gratefully acknowledged.
Publisher
Royal Society of Chemistry (RSC)
Journal
Chem. Commun.
ISSN
13597345
DOI
10.1039/c5cc00193e
PubMed ID
25735485
Handle URI
http://hdl.handle.net/10754/563962
Collections
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Chemical and Biological Engineering Program; KAUST Catalysis Center (KCC)