Boron nitride nanosheets as improved and reusable substrates for gold nanoparticles enabled surface enhanced Raman spectroscopy
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical and Biological Engineering Program
Preprint Posting Date2015-03-11
Permanent link to this recordhttp://hdl.handle.net/10754/563956
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AbstractAtomically thin boron nitride (BN) nanosheets have been found to be excellent substrates for noble metal particles enabled surface enhanced Raman spectroscopy (SERS), thanks to their good adsorption of aromatic molecules, high thermal stability and weak Raman scattering. Faceted gold (Au) nanoparticles have been synthesized on BN nanosheets using a simple but controllable and reproducible sputtering and annealing method. The size and density of the Au particles can be controlled by sputtering time, current and annealing temperature etc. Under the same sputtering and annealing conditions, the Au particles on BN of different thicknesses show various sizes because the surface diffusion coefficients of Au depend on the thickness of BN. Intriguingly, decorated with similar morphology and distribution of Au particles, BN nanosheets exhibit better Raman enhancements than silicon substrates as well as bulk BN crystals. Additionally, BN nanosheets show no noticeable SERS signal and hence cause no interference to the Raman signal of the analyte. The Au/BN substrates can be reused by heating in air to remove the adsorbed analyte without loss of SERS enhancement. This journal is © the Owner Societies 2015.
CitationCai, Q., Li, L. H., Yu, Y., Liu, Y., Huang, S., Chen, Y., … Taniguchi, T. (2015). Boron nitride nanosheets as improved and reusable substrates for gold nanoparticles enabled surface enhanced Raman spectroscopy. Physical Chemistry Chemical Physics, 17(12), 7761–7766. doi:10.1039/c5cp00532a
SponsorsL. H. Li thanks the financial support from ADPRF2014 and CRGS2015. Y. Chen thanks the funding from the Australian Research Council under the Discovery Program.
PublisherRoyal Society of Chemistry (RSC)
JournalPhys. Chem. Chem. Phys.