Show simple item record

dc.contributor.authorRiache, Nassima
dc.contributor.authorCallens, Emmanuel
dc.contributor.authorEspinas, Jeff
dc.contributor.authorDéry, Alexandre
dc.contributor.authorSamantaray, Manoja
dc.contributor.authorDey, Raju
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-03T12:19:58Z
dc.date.available2015-08-03T12:19:58Z
dc.date.issued2015
dc.identifier.issn20444753
dc.identifier.doi10.1039/c4cy00663a
dc.identifier.urihttp://hdl.handle.net/10754/563931
dc.description.abstractMetathesis of linear alkanes catalyzed by the well-defined precursor (≡Si-O-WMe5) affords a wide distribution of linear alkanes from methane up to triacontane. Olefin metathesis using the same catalyst and under the same reaction conditions gives a very striking different distribution of linear α-olefins and internal olefins. This shows that olefin and alkane metathesis processes occur via very different pathways.
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleStriking difference between alkane and olefin metathesis using the well-defined precursor [≡Si-O-WMe5]: Indirect evidence in favour of a bifunctional catalyst W alkylidene-hydride
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCatal. Sci. Technol.
kaust.personRiache, Nassima
kaust.personCallens, Emmanuel
kaust.personEspinas, Jeff
kaust.personSamantaray, Manoja
kaust.personDey, Raju
kaust.personBasset, Jean-Marie
kaust.personDéry, Alexandre


This item appears in the following Collection(s)

Show simple item record