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dc.contributor.authorShekhah, Osama
dc.contributor.authorCadiau, Amandine
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2015-08-03T12:19:56Z
dc.date.available2015-08-03T12:19:56Z
dc.date.issued2015
dc.identifier.citationShekhah, O., Cadiau, A., & Eddaoudi, M. (2015). Fabrication and non-covalent modification of highly oriented thin films of a zeolite-like metal–organic framework (ZMOF) with rho topology. CrystEngComm, 17(2), 290–294. doi:10.1039/c4ce01402b
dc.identifier.issn14668033
dc.identifier.doi10.1039/c4ce01402b
dc.identifier.urihttp://hdl.handle.net/10754/563930
dc.description.abstractHere we report the fabrication of the first thin film of a zeolite-like metal-organic framework (ZMOF) with rho topology (rho-ZMOF-1, ([In48(HImDC)96]48-)n) in a highly oriented fashion on a gold-functionalized substrate. The oriented rho-ZMOF-1 film was functionalized by non-covalent modification via post-synthetic exchange of different probe molecules, such as acridine yellow, methylene blue, and Nile red. In addition, encapsulation of a porphyrin moiety was achieved via in situ synthesis and construction of the rho-ZMOF. Adsorption kinetics of volatile organic compounds on rho-ZMOF-1 thin films was also investigated. This study suggests that rho-ZMOF-1 thin films can be regarded as a promising platform for various applications such as sensing and catalysis. This journal is
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleFabrication and non-covalent modification of highly oriented thin films of a zeolite-like metal-organic framework (ZMOF) with rho topology
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCrystEngComm
kaust.personShekhah, Osama
kaust.personCadiau, Amandine
kaust.personEddaoudi, Mohamed


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