Show simple item record

dc.contributor.authorSo, Monica
dc.contributor.authorBeyzavi, M. Hassan
dc.contributor.authorSawhney, Rohan
dc.contributor.authorShekhah, Osama
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorAl-Juaid, Salih Salem
dc.contributor.authorHupp, Joseph T.
dc.contributor.authorFarha, Omar K.
dc.date.accessioned2015-08-03T12:19:53Z
dc.date.available2015-08-03T12:19:53Z
dc.date.issued2015
dc.identifier.issn13597345
dc.identifier.doi10.1039/c4cc05727a
dc.identifier.urihttp://hdl.handle.net/10754/563929
dc.description.abstractHerein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
dc.description.sponsorshipO.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).
dc.publisherRoyal Society of Chemistry (RSC)
dc.titlePost-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem. Commun.
dc.contributor.institutionDepartment of Chemistry, Northwestern University, 2145 Sheridan RoadEvanston, IL, United States
dc.contributor.institutionDepartment of Chemistry, King Abdulaziz UniversityJeddah, Saudi Arabia
kaust.personShekhah, Osama
kaust.personEddaoudi, Mohamed


This item appears in the following Collection(s)

Show simple item record