Space-charge-mediated anomalous ferroelectric switching in P(VDF-TrEE) polymer films
KAUST DepartmentAdvanced Nanofabrication, Imaging and Characterization Core Lab
KAUST Solar Center (KSC)
Laboratory of Nano Oxides for Sustainable Energy
Material Science and Engineering Program
Nanofabrication Core Lab
Physical Science and Engineering (PSE) Division
Online Publication Date2014-10-16
Print Publication Date2014-11-12
Permanent link to this recordhttp://hdl.handle.net/10754/563857
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AbstractWe report on the switching dynamics of P(VDF-TrEE) copolymer devices and the realization of additional substable ferroelectric states via modulation of the coupling between polarizations and space charges. The space-charge-limited current is revealed to be the dominant leakage mechanism in such organic ferroelectric devices, and electrostatic interactions due to space charges lead to the emergence of anomalous ferroelectric loops. The reliable control of ferroelectric switching in P(VDF-TrEE) copolymers opens doors toward engineering advanced organic memories with tailored switching characteristics.
CitationHu, W., Wang, Z., Du, Y., Zhang, X.-X., & Wu, T. (2014). Space-Charge-Mediated Anomalous Ferroelectric Switching in P(VDF–TrEE) Polymer Films. ACS Applied Materials & Interfaces, 6(21), 19057–19063. doi:10.1021/am5050136
SponsorsThis work is supported by KAUST.
PublisherAmerican Chemical Society (ACS)
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