Show simple item record

Synthesis, crystal structure and reactivity studies of iron complexes with pybox ligands

dc.contributor.authorChen, Tao
dc.contributor.authorYang, Limin
dc.contributor.authorGong, Dirong
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2015-08-03T12:15:37Z
dc.date.available2015-08-03T12:15:37Z
dc.date.issued2014-11
dc.identifier.citationChen, T., Yang, L., Gong, D., & Huang, K.-W. (2014). Synthesis, crystal structure and reactivity studies of iron complexes with pybox ligands. Inorganica Chimica Acta, 423, 320–325. doi:10.1016/j.ica.2014.08.050
dc.identifier.issn00201693
dc.identifier.doi10.1016/j.ica.2014.08.050
dc.identifier.urihttp://hdl.handle.net/10754/563822
dc.description.abstractIron(II) complexes, [Fe(2,6-bis(4,4-dimethyl-1,3-oxazolin-2-yl)pyridine)Cl2] ((Fe(Me2-pybox)Cl2), 3) and [Fe(2,6-bis(4,4-diphenyl-1,3-oxazolin-2-yl)pyridine)Cl2] ((Fe(Ph2-pybox)Cl2), 4), have been synthesized and characterized by X-ray crystallographic analysis. Upon treatment of complex 3 with silver triflate and 4 with acetonitrile, [Fe(Me2-pybox)(CH3CN)OTf2] (5) and [Fe(Ph2-pybox)(CH3CN)2Cl][FeCl3] (6) were obtained, respectively. The bulkier phenyl substitutes were found not only to cause the elongation of the N-Fe bonds but also influence the reactivity of the Fe center.
dc.description.sponsorshipWe are grateful for the financial support from King Abdullah University of Science and Technology. We thank Ms Geok Kheng Tan (NUS) for her kindly help in X-ray crystallographic analysis. Financial supports from the Natural Science Foundation of China (21302170, 21304050), the Science Foundation of Zhejiang Sci-Tech University (1201839-Y), the Program for Zhejiang Leading Team of Science and Technology Innovation (2010R50038-20) were also greatly appreciated.
dc.publisherElsevier BV
dc.subjectCrystal structure
dc.subjectIron complex
dc.subjectPybox ligand
dc.subjectReactivity
dc.subjectSynthesis
dc.titleSynthesis, crystal structure and reactivity studies of iron complexes with pybox ligands
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalInorganica Chimica Acta
dc.contributor.institutionMOE Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Natl. Base for International Cooperation in Science and Technology of Textiles and Daily Chemistry, Zhejiang Sci-Tech UniversityHangzhou, China
dc.contributor.institutionCollege of Materials, Chemistry and Chemical Engineering, Hangzhou Normal UniversityHangzhou, China
dc.contributor.institutionDepartment of Polymer Science and Engineering, Grubbs Institute, Ningbo UniversityNingbo, China
kaust.personGong, Dirong
kaust.personHuang, Kuo-Wei
kaust.personChen, Tao
kaust.personYang, Limin
dc.relation.issupplementedbyDOI:10.5517/ccyj33n
dc.relation.issupplementedbyDOI:10.5517/ccyj34p
dc.relation.issupplementedbyDOI:10.5517/ccyj30k
dc.relation.issupplementedbyDOI:10.5517/ccyj31l
dc.relation.issupplementedbyDOI:10.5517/ccyj32m
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879411: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj33n. DOI: <a href="https://doi.org/10.5517/ccyj33n">10.5517/ccyj33n</a> HANDLE: <a href="http://hdl.handle.net/10754/624708">10754/624708</a></li><li><i>[Dataset]</i> <br/> Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879412: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj34p. DOI: <a href="https://doi.org/10.5517/ccyj34p">10.5517/ccyj34p</a> HANDLE: <a href="http://hdl.handle.net/10754/624709">10754/624709</a></li><li><i>[Dataset]</i> <br/> Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879408: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj30k. DOI: <a href="https://doi.org/10.5517/ccyj30k">10.5517/ccyj30k</a> HANDLE: <a href="http://hdl.handle.net/10754/624705">10754/624705</a></li><li><i>[Dataset]</i> <br/> Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879409: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj31l. DOI: <a href="https://doi.org/10.5517/ccyj31l">10.5517/ccyj31l</a> HANDLE: <a href="http://hdl.handle.net/10754/624706">10754/624706</a></li><li><i>[Dataset]</i> <br/> Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879410: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj32m. DOI: <a href="https://doi.org/10.5517/ccyj32m">10.5517/ccyj32m</a> HANDLE: <a href="http://hdl.handle.net/10754/624707">10754/624707</a></li></ul>


This item appears in the following Collection(s)

Show simple item record