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    Synthesis, crystal structure and reactivity studies of iron complexes with pybox ligands

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    Type
    Article
    Authors
    Chen, Tao
    Yang, Limin
    Gong, Dirong
    Huang, Kuo-Wei cc
    KAUST Department
    Biological and Environmental Sciences and Engineering (BESE) Division
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2014-11
    Permanent link to this record
    http://hdl.handle.net/10754/563822
    
    Metadata
    Show full item record
    Abstract
    Iron(II) complexes, [Fe(2,6-bis(4,4-dimethyl-1,3-oxazolin-2-yl)pyridine)Cl2] ((Fe(Me2-pybox)Cl2), 3) and [Fe(2,6-bis(4,4-diphenyl-1,3-oxazolin-2-yl)pyridine)Cl2] ((Fe(Ph2-pybox)Cl2), 4), have been synthesized and characterized by X-ray crystallographic analysis. Upon treatment of complex 3 with silver triflate and 4 with acetonitrile, [Fe(Me2-pybox)(CH3CN)OTf2] (5) and [Fe(Ph2-pybox)(CH3CN)2Cl][FeCl3] (6) were obtained, respectively. The bulkier phenyl substitutes were found not only to cause the elongation of the N-Fe bonds but also influence the reactivity of the Fe center.
    Citation
    Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2014). Synthesis, crystal structure and reactivity studies of iron complexes with pybox ligands. Inorganica Chimica Acta, 423, 320–325. doi:10.1016/j.ica.2014.08.050
    Sponsors
    We are grateful for the financial support from King Abdullah University of Science and Technology. We thank Ms Geok Kheng Tan (NUS) for her kindly help in X-ray crystallographic analysis. Financial supports from the Natural Science Foundation of China (21302170, 21304050), the Science Foundation of Zhejiang Sci-Tech University (1201839-Y), the Program for Zhejiang Leading Team of Science and Technology Innovation (2010R50038-20) were also greatly appreciated.
    Publisher
    Elsevier BV
    Journal
    Inorganica Chimica Acta
    DOI
    10.1016/j.ica.2014.08.050
    Relations
    Is Supplemented By:
    • [Dataset]
      Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879411: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj33n. DOI: 10.5517/ccyj33n HANDLE: 10754/624708
    • [Dataset]
      Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879412: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj34p. DOI: 10.5517/ccyj34p HANDLE: 10754/624709
    • [Dataset]
      Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879408: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj30k. DOI: 10.5517/ccyj30k HANDLE: 10754/624705
    • [Dataset]
      Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879409: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj31l. DOI: 10.5517/ccyj31l HANDLE: 10754/624706
    • [Dataset]
      Chen, T., Yang, L., Gong, D., & Huang, K.-W. (2015). CCDC 879410: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyj32m. DOI: 10.5517/ccyj32m HANDLE: 10754/624707
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.ica.2014.08.050
    Scopus Count
    Collections
    Articles; Biological and Environmental Science and Engineering (BESE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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