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dc.contributor.authorDavaasuren, Bambar
dc.contributor.authorDashjav, Enkhtsetseg
dc.contributor.authorRothenberger, Alexander
dc.date.accessioned2015-08-03T12:10:38Z
dc.date.available2015-08-03T12:10:38Z
dc.date.issued2014-10-19
dc.identifier.citationDavaasuren, B., Dashjav, E., & Rothenberger, A. (2014). Synthesis and Characterization of the Ternary Telluroargentate K4[Ag18Te11]. Zeitschrift Für Anorganische Und Allgemeine Chemie, 640(14), 2939–2944. doi:10.1002/zaac.201400407
dc.identifier.issn00442313
dc.identifier.doi10.1002/zaac.201400407
dc.identifier.urihttp://hdl.handle.net/10754/563802
dc.description.abstractThe ternary potassium telluroargentate(I), K4[Ag18Te11], was prepared by solvothermal synthesis in ethylenediamine at 160 °C. It crystallizes in the cubic space group Fm3¯ m (no. 225) with the cell parameter a = 18.6589(6) Å. The crystal structure can be described as a [Ag18Te11]4- three-dimensional anionic framework with the voids accommodating potassium cations. Chemical bonding analysis reveals polar covalent Ag-Te bonds and considerable Ag-Ag interactions, which support the complex anionic character of the structure. The compound is thermally stable up to 450 °C in an inert atmosphere.
dc.description.sponsorshipThis research was supported by King Abdullah University of Science and Technology (KAUST) baseline funding.
dc.publisherWiley
dc.subjectAnionic framework
dc.subjectCOHP bonding analysis
dc.subjectSilver
dc.subjectSolvothermal synthesis
dc.subjectTellurium
dc.subjectTelluroargentate
dc.titleSynthesis and characterization of the ternary telluroargentate K4[Ag18Te11]
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalZeitschrift für anorganische und allgemeine Chemie
dc.contributor.institutionMaterials Synthesis and Processing Division, Institute for Energy and Climate Research, Forschungszentrum Jülich GmbHJülich, Germany
kaust.personDavaasuren, Bambar
kaust.personRothenberger, Alexander
dc.date.published-online2014-10-19
dc.date.published-print2014-11


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