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dc.contributor.authorSolovyeva, Vera A.
dc.contributor.authorVu, Khanh B.
dc.contributor.authorMerican, Zulkifli
dc.contributor.authorSougrat, Rachid
dc.contributor.authorRodionov, Valentin O.
dc.date.accessioned2015-08-03T12:10:25Z
dc.date.available2015-08-03T12:10:25Z
dc.date.issued2014-09-26
dc.identifier.citationSolovyeva, V. A., Vu, K. B., Merican, Z., Sougrat, R., & Rodionov, V. O. (2014). One-Pot Synthesis of Au@SiO2 Catalysts: A Click Chemistry Approach. ACS Combinatorial Science, 16(10), 513–517. doi:10.1021/co5000932
dc.identifier.issn21568952
dc.identifier.pmid25229602
dc.identifier.doi10.1021/co5000932
dc.identifier.urihttp://hdl.handle.net/10754/563796
dc.description.abstractUsing the copper-catalyzed azide-alkyne cycloaddition "click" reaction, a library of triazole amphiphiles with a variety of functional polar "heads" and hydrophobic or superhydrophobic "tails" was synthesized. The amphiphiles were evaluated for their ability to stabilize small Au nanoparticles, and, at the same time, serve as templates for nanocasting porous SiO2. One of the Au@SiO2 materials thus prepared was found to be a highly active catalyst for the Au nanoparticle-catalyzed regioselective hydroamination of alkynes.
dc.description.sponsorshipSupport from KAUST baseline funding program is acknowledged with thanks.
dc.publisherAmerican Chemical Society (ACS)
dc.subjectclick chemistry
dc.subjectfluorous surfactant
dc.subjectgold nanoparticles
dc.subjecthydroamination
dc.titleOne-pot synthesis of Au@SiO2 catalysts: A click chemistry approach
dc.typeArticle
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Lab
dc.contributor.departmentCore Labs
dc.contributor.departmentImaging and Characterization Core Lab
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalACS Combinatorial Science
kaust.personSougrat, Rachid
dc.date.published-online2014-09-26
dc.date.published-print2014-10-13


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