(Gold core) at (ceria shell) nanostructures for plasmon-enhanced catalytic reactions under visible light
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Water Desalination and Reuse Research Center (WDRC)
Environmental Science and Engineering Program
Environmental Nanotechnology Lab
Online Publication Date2014-07-23
Print Publication Date2014-08-26
Permanent link to this recordhttp://hdl.handle.net/10754/563713
MetadataShow full item record
AbstractDriving catalytic reactions with sunlight is an excellent example of sustainable chemistry. A prerequisite of solar-driven catalytic reactions is the development of photocatalysts with high solar-harvesting efficiencies and catalytic activities. Herein, we describe a general approach for uniformly coating ceria on monometallic and bimetallic nanocrystals through heterogeneous nucleation and growth. The method allows for control of the shape, size, and type of the metal core as well as the thickness of the ceria shell. The plasmon shifts of the Au@CeO2 nanostructures resulting from the switching between Ce(IV) and Ce(III) are observed. The selective oxidation of benzyl alcohol to benzaldehyde, one of the fundamental reactions for organic synthesis, performed under both broad-band and monochromatic light, demonstrates the visible-light-driven catalytic activity and reveals the synergistic effect on the enhanced catalysis of the Au@CeO2 nanostructures. © 2014 American Chemical Society.
SponsorsThis work was supported by Hong Kong RGC GRF (Ref. No. CUHK403312, Project Code 2130320) and NNSFC (Ref. No. 21229101).
PublisherAmerican Chemical Society (ACS)