Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks
KAUST DepartmentPhysical Sciences and Engineering (PSE) Division
Materials Science and Engineering Program
KAUST Solar Center (KSC)
Laboratory of Nano Oxides for Sustainable Energy
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AbstractIn this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.
SponsorsThe authors thank Prof. Tao Wu and Jian Lin for topology analysis. Q.Z. acknowledges AcRF Tier 1 (RG 16/12) and Tier 2 (ARC 2/13 and ARC 20/12) from MOE and the CREATE program (Nanomaterials for Energy and Water Management) from NRF Singapore. This work was also supported by the National Natural Science Foundation of China (Grant 21271009).
PublisherAmerican Chemical Society (ACS)
Is Supplemented ByLu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029958: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krgw
Lu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029959: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krhx
Lu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029960: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krjy