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Hydrogenation of esters catalyzed by ruthenium PN3-Pincer complexes containing an aminophosphine arm

dc.contributor.authorChen, Tao
dc.contributor.authorLi, Huaifeng
dc.contributor.authorQu, Shuanglin
dc.contributor.authorZheng, Bin
dc.contributor.authorHe, Lipeng
dc.contributor.authorLai, Zhiping
dc.contributor.authorWang, Zhixiang
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2015-08-03T12:06:52Z
dc.date.available2015-08-03T12:06:52Z
dc.date.issued2014-07-31
dc.identifier.issn02767333
dc.identifier.doi10.1021/om500549t
dc.identifier.urihttp://hdl.handle.net/10754/563699
dc.description.abstractHydrogenation of esters under mild conditions was achieved using air-stable ruthenium PN3-pincer complexes containing an aminophosphine arm. High efficiency was achieved even in the presence of water. DFT studies suggest a bimolecular proton shuttle mechanism which allows H2 to be activated by the relatively stable catalyst with a reasonably low transition state barrier. © 2014 American Chemical Society.
dc.publisherAmerican Chemical Society (ACS)
dc.titleHydrogenation of esters catalyzed by ruthenium PN3-Pincer complexes containing an aminophosphine arm
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganometallics
dc.contributor.institutionMOE Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Natl. Base for International Cooperation in Science and Technology of Textiles and Daily Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China
dc.contributor.institutionCollege of Chemistry and Chemical Engineering, University of the Chinese, Academy of Sciences, Beijing 100049, China
kaust.personLi, Huaifeng
kaust.personZheng, Bin
kaust.personHe, Lipeng
kaust.personLai, Zhiping
kaust.personHuang, Kuo-Wei
kaust.personChen, Tao
dc.relation.issupplementedbyDOI:10.5517/cc136h71
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Chen, T., Li, H., Qu, S., Zheng, B., He, L., Lai, Z., … Huang, K.-W. (2014). CCDC 1019132: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc136h71. DOI: <a href="https://doi.org/10.5517/cc136h71">10.5517/cc136h71</a> HANDLE: <a href="http://hdl.handle.net/10754/624358">10754/624358</a></li></ul>
dc.date.published-online2014-07-31
dc.date.published-print2014-08-11


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