4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes
Zaworotko, Michael J.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
KAUST Grant NumberFIC/2010/06
Online Publication Date2014-04-14
Print Publication Date2014-05-07
Permanent link to this recordhttp://hdl.handle.net/10754/563539
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AbstractA two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.
CitationSchoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). 4,6-Connected fsb Topology Networks Obtained through Two-Step Crystal Engineering of Decorated Trigonal Prismatic Nodes. Crystal Growth & Design, 14(5), 2115–2117. doi:10.1021/cg500205f
SponsorsThis work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).
PublisherAmerican Chemical Society (ACS)
JournalCrystal Growth & Design
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Schoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010338: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xbkw. DOI: 10.5517/cc12xbkw HANDLE: 10754/624342
Schoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010339: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xblx. DOI: 10.5517/cc12xblx HANDLE: 10754/624343