Thermoelectric properties of strontium titanate superlattices incorporating niobium oxide nanolayers
KAUST DepartmentCore Labs
Functional Nanomaterials and Devices Research Group
Imaging and Characterization Core Lab
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Online Publication Date2014-04-09
Print Publication Date2014-04-22
Permanent link to this recordhttp://hdl.handle.net/10754/563506
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AbstractA novel superlattice structure based on epitaxial nanoscale layers of NbOx and Nb-doped SrTiO3 is fabricated using a layer-by-layer approach on lattice matched LAO substrates. The absolute Seebeck coefficient and electrical conductivity of the [(NbOx) a/(Nb-doped SrTiO3)b]20 superlattices (SLs) were found to increase with decreasing layer thickness ratio (a/b ratio), reaching, at high temperatures, a power factor that is comparable to epitaxial Nb-doped SrTiO3 (STNO) films (∼0.7 W m-1 K-1). High temperature studies reveal that the SLs behave as n-type semiconductors and undergo an irreversible change at a varying crossover temperature that depends on the a/b ratio. By use of high resolution X-ray photoelectron spectroscopy and X-ray diffraction, the irreversible changes are identified to be due to a phase transformation from cubic NbO to orthorhombic Nb2O5, which limits the highest temperature of stable operation of the superlattice to 950 K. © 2014 American Chemical Society.
CitationKumar, S. R. S., Hedhili, M. N., Cha, D., Tritt, T. M., & Alshareef, H. N. (2014). Thermoelectric Properties of Strontium Titanate Superlattices Incorporating Niobium Oxide Nanolayers. Chemistry of Materials, 26(8), 2726–2732. doi:10.1021/cm500646f
SponsorsS.R.S.K., H.N.A., and T.M.T. acknowledge the financial support of the KAUST Competitive Faculty-Initiated Collaboration Grant.
PublisherAmerican Chemical Society (ACS)
JournalChemistry of Materials