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dc.contributor.authorLuebke, Ryan
dc.contributor.authorWeselinski, Lukasz Jan
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorChen, Zhijie
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2015-08-03T11:47:18Z
dc.date.available2015-08-03T11:47:18Z
dc.date.issued2014-01-17
dc.identifier.issn15287483
dc.identifier.doi10.1021/cg401802s
dc.identifier.urihttp://hdl.handle.net/10754/563387
dc.description.abstractHere we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.
dc.description.sponsorshipAuthors gratefully acknowledge KAUST for funding.
dc.publisherAmerican Chemical Society (ACS)
dc.titleMicroporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCrystal Growth & Design
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620, United States
kaust.personLuebke, Ryan
kaust.personWeselinski, Lukasz Jan
kaust.personBelmabkhout, Youssef
kaust.personEddaoudi, Mohamed
kaust.personChen, Zhijie
dc.relation.issupplementedbyDOI:10.5517/cc11q542
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Luebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). CCDC 974613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11q542. DOI: <a href="https://doi.org/10.5517/cc11q542">10.5517/cc11q542</a> HANDLE: <a href="http://hdl.handle.net/10754/624294">10754/624294</a></li></ul>
dc.date.published-online2014-01-17
dc.date.published-print2014-02-05


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