The use of a well-defined surface organometallic complex as a probe molecule: [(≡SiO)Ta<sup>V</sup>Cl<sub>2</sub>Me<sub>2</sub>] shows different isolated silanol sites on the silica surface

Type
Article
Authors
Chen, Yin
Zheng, Bin cc
Abou-Hamad, Edy cc
Hamieh, Ali Imad Ali cc
Hamzaoui, Bilel cc
Huang, Kuo-Wei cc
Basset, Jean-Marie cc
KAUST Department
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
KAUST Solar Center (KSC)
HCL
Date
2014

Metadata
Show full item record
Abstract
TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is © the Partner Organisations 2014.
Sponsors
We acknowledge the generous financial support from KAUST.
Publisher
Royal Society of Chemistry (RSC)
Journal
Chem. Commun.
ISSN
13597345
DOI
10.1039/c4cc04277h
PubMed ID
25142307
Handle URI
http://hdl.handle.net/10754/563275
Collections
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)