• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguideTheses and Dissertations LibguideSubmit an Item

    Statistics

    Display statistics

    The use of a well-defined surface organometallic complex as a probe molecule: $[(=SiO)Ta^{V}Cl_{2}Me_{2}]$ shows different isolated silanol sites on the silica surface

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Type
    Article
    Authors
    Chen, Yin
    Zheng, Bin cc
    Abou-Hamad, Edy cc
    Hamieh, Ali Imad Ali cc
    Hamzaoui, Bilel cc
    Huang, Kuo-Wei cc
    Basset, Jean-Marie cc
    KAUST Department
    Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    KAUST Solar Center (KSC)
    Physical Science and Engineering (PSE) Division
    Date
    2014
    Permanent link to this record
    http://hdl.handle.net/10754/563275
    
    Metadata
    Show full item record
    Abstract
    TaVCl2Me3 reacts with silica(700) and produces two different [(≡SiO)TaVCl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach. This journal is © the Partner Organisations 2014.
    Citation
    Chen, Y., Zheng, B., Abou-Hamad, E., Hamieh, A., Hamzaoui, B., Huang, K., & Basset, J. (2014). The use of a well-defined surface organometallic complex as a probe molecule: [(SiO)TaVCl2Me2] shows different isolated silanol sites on the silica surface. Chem. Commun., 50(79), 11721–11723. doi:10.1039/c4cc04277h
    Sponsors
    We acknowledge the generous financial support from KAUST.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chem. Commun.
    DOI
    10.1039/c4cc04277h
    PubMed ID
    25142307
    ae974a485f413a2113503eed53cd6c53
    10.1039/c4cc04277h
    Scopus Count
    Collections
    Articles; Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC); Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)

    entitlement

    Related articles

    • Alkane metathesis with the tantalum methylidene [(≡SiO)Ta(═CH2)Me2]/[(≡SiO)2Ta(═CH2)Me] generated from well-defined surface organometallic complex [(≡SiO)Ta(V)Me4].
    • Authors: Chen Y, Abou-hamad E, Hamieh A, Hamzaoui B, Emsley L, Basset JM
    • Issue date: 2015 Jan 21
    • [(≡SiO)Ta(V)Cl2Me2]: a well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene.
    • Authors: Chen Y, Callens E, Abou-Hamad E, Merle N, White AJ, Taoufik M, Copéret C, Le Roux E, Basset JM
    • Issue date: 2012 Nov 19
    • Successive heterolytic cleavages of H2 achieve N2 splitting on silica-supported tantalum hydrides: a DFT proposed mechanism.
    • Authors: Solans-Monfort X, Chow C, Gouré E, Kaya Y, Basset JM, Taoufik M, Quadrelli EA, Eisenstein O
    • Issue date: 2012 Jul 2
    • Well-Defined Molybdenum Oxo Alkyl Complex Supported on Silica by Surface Organometallic Chemistry: A Highly Active Olefin Metathesis Precatalyst.
    • Authors: Merle N, Le Quéméner F, Bouhoute Y, Szeto KC, De Mallmann A, Barman S, Samantaray MK, Delevoye L, Gauvin RM, Taoufik M, Basset JM
    • Issue date: 2017 Feb 15
    • A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst.
    • Authors: Conley MP, Mougel V, Peryshkov DV, Forrest WP Jr, Gajan D, Lesage A, Emsley L, Copéret C, Schrock RR
    • Issue date: 2013 Dec 26
    DSpace software copyright © 2002-2022  DuraSpace
    Quick Guide | Contact Us | KAUST University Library
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.