Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid
Type
ArticleAuthors
Patil, UmeshSaih, Youssef
Abou-Hamad, Edy

Hamieh, Ali Imad Ali

Pelletier, Jeremie

Basset, Jean-Marie

KAUST Department
Ali I. Al-Naimi Petroleum Engineering Research Center (ANPERC)Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2014Permanent link to this record
http://hdl.handle.net/10754/563243
Metadata
Show full item recordAbstract
A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal isCitation
Patil, U., Saih, Y., Abou-Hamad, E., Hamieh, A., Pelletier, J. D. A., & Basset, J. M. (2014). Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid. Chem. Commun., 50(82), 12348–12351. doi:10.1039/c4cc04950kSponsors
We gratefully acknowledge King Abdullah University of Science and Technology (KAUST) and Saudi Basic Industries Corporation (SABIC) for financial support.Publisher
Royal Society of Chemistry (RSC)Journal
Chem. Commun.PubMed ID
25182752ae974a485f413a2113503eed53cd6c53
10.1039/c4cc04950k
Scopus Count
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