Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid
Hamieh, Ali Imad Ali
KAUST DepartmentAli I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/563243
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AbstractA Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. This journal is
CitationPatil, U., Saih, Y., Abou-Hamad, E., Hamieh, A., Pelletier, J. D. A., & Basset, J. M. (2014). Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid. Chem. Commun., 50(82), 12348–12351. doi:10.1039/c4cc04950k
SponsorsWe gratefully acknowledge King Abdullah University of Science and Technology (KAUST) and Saudi Basic Industries Corporation (SABIC) for financial support.
PublisherRoyal Society of Chemistry (RSC)
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