Synthesis and properties of the metallo-supramolecular polymer hydrogel poly[methyl vinyl ether-alt-mono-sodium maleate]·AgNO3: Ag+/Cu2+ ion exchange and effective antibacterial activity
Al-Dossary, Mona S.
Behzad, Ali Reza
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Advanced Nanofabrication, Imaging and Characterization Core Lab
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Imaging and Characterization Core Lab
KAUST Solar Center (KSC)
Marine Microbial Ecology Research Group
Marine Science Program
Physical Science and Engineering (PSE) Division
Red Sea Research Center (RSRC)
Permanent link to this recordhttp://hdl.handle.net/10754/563236
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AbstractThe commercial polymeric anhydride poly(methyl vinyl ether-alt-maleic anhydride) (PVM/MA) is converted by reaction with NaOH to give poly(methyl vinyl ether-alt-mono-sodium maleate) (PVM/Na-MA). By addition of AgNO 3-solution, the formation of the silver(i) supramolecular polymer hydrogel poly[methyl vinyl ether-alt-mono-sodium maleate]·AgNO 3 is reported. Freeze-dried samples of the hydrogel show a mesoporous network of polycarboxylate ligands that are crosslinked by silver(i) cations. In the intact hydrogel, ion-exchange studies are reported and it is shown that Ag+ ions can be exchanged by copper(ii) cations without disintegration of the hydrogel. The silver(i) hydrogel shows effective antibacterial activity and potential application as burn wound dressing. © the Partner Organisations 2014.
SponsorsThe authors thank Dr Lan Zhao, Dr Omar El Tall and Dr Xian-rong Guo from the King Abdullah University of Science and Technology (KAUST) Core Laboratories for their help in the characterization. Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
PublisherRoyal Society of Chemistry (RSC)
JournalJournal of Materials Chemistry B