Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species
KAUST DepartmentKAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
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AbstractExtensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. © 2014 the Partner Organisations.
SponsorsThe authors thank Dr Manoja Samantaray and Dr Raju Dey for their contribution in the synthesis of the silica supported W-catalyst. Research leading to these results has received funding from the University of King Abdullah University of Science and Technology.
PublisherRoyal Society of Chemistry (RSC)
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