Porous organic polymers with anchored aldehydes: A new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

Type
Article
Authors
Guillerm, Vincent cc
Weselinski, Lukasz Jan cc
Al Kordi, Mohamed
Haja Mohideen, Mohamed Infas
Belmabkhout, Youssef cc
Cairns, Amy
Eddaoudi, Mohamed cc
KAUST Department
Advanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2014
Permanent link to this record
http://hdl.handle.net/10754/563173

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Abstract
A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties. © 2014 The Royal Society of Chemistry.
Citation
Guillerm, V., Weseliński, Ł. J., Alkordi, M., Mohideen, M. I. H., Belmabkhout, Y., Cairns, A. J., & Eddaoudi, M. (2014). Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties. Chemical Communications, 50(16), 1937. doi:10.1039/c3cc48228f
Publisher
Royal Society of Chemistry (RSC)
Journal
Chemical Communications
DOI
10.1039/c3cc48228f
PubMed ID
24445684
Collections
Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program